First Mixed Fluoro−Chloro Group 4 Organometallics: Synthesis and Spectroscopic and Structural Characterization of [{(C5Me5)ZrF2Cl}4], [{(C5Me5)HfF2Cl}4], [(C5Me5)4Zr4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me5)4Hf4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me4Et)2ZrClF], and [(C5Me5)2HfClF]

Eamonn F. Murphy, Thomas Lübben, Axel Herzog, Herbert W. Roesky, Alojz Demsar, Mathias Noltemeyer, Hans-Georg Schmidt

Open source

DOI: 10.1021/ic950822a
Published: 1996-01-01
Container: Inorganic Chemistry
Publisher: American Chemical Society (ACS)
Open access: unknown

Credibility signals

uncertain Score 64/100 under policy 1.0.0. This is a metadata assessment, not a judgment of the paper's conclusions.

Show all credibility signals

supportingDOI registered: A matching record was returned by Crossref. Source: Crossref; license: CC0 metadata
supportingDOI resolves: A matching record was returned by Crossref. Source: Crossref; license: CC0 metadata
not scoredDirectory of Open Access Journals: No matching DOAJ record was present in this response. No allow-list match; this is not evidence of low credibility. Source: DOAJ; license: CC0
not scoredMEDLINE indexed: Not checked or no result supplied; no credibility inference made. Source: No authority result supplied; license: Unknown
not scoredOpenAlex core source: Not checked or no result supplied; no credibility inference made. Source: No authority result supplied; license: Unknown
not scoredKnown publisher allow-list: Not checked or no result supplied; no credibility inference made. Source: No authority result supplied; license: Unknown
not scoredROR affiliation: Not checked or no result supplied; no credibility inference made. Source: No authority result supplied; license: Unknown
not scoredRetraction Watch retraction: No retraction notice matched this DOI in the deployed snapshot. No matching event found; coverage may be incomplete. Source: Retraction Watch; license: CC BY 4.0
not scoredRetraction Watch expression of concern: No expression of concern notice matched this DOI in the deployed snapshot. No matching event found; coverage may be incomplete. Source: Retraction Watch; license: CC BY 4.0
not scoredRetraction Watch correction: No correction notice matched this DOI in the deployed snapshot. No matching event found; coverage may be incomplete. Source: Retraction Watch; license: CC BY 4.0
not scoredRetraction Watch reinstatement: No reinstatement notice matched this DOI in the deployed snapshot. No matching event found; coverage may be incomplete. Source: Retraction Watch; license: CC BY 4.0
not scoredOpen access status: Not checked or no result supplied; no credibility inference made. Source: No authority result supplied; license: Unknown
not scoredPublication license: Not checked or no result supplied; no credibility inference made. Source: No authority result supplied; license: Unknown
not scoredPublication version: A publication version was supplied but is not scored. Source: Normalized work metadata; license: Caller-provided; provenance license not supplied to scorer
supportingMetadata completeness: All 6 scored descriptive metadata groups are present. Source: Normalized work metadata; license: Caller-provided; provenance license not supplied to scorer

Cite this work

BibTeX

@article{allodium:10.1021/ic950822a,
  title = {First Mixed Fluoro−Chloro Group 4 Organometallics:  Synthesis and Spectroscopic and Structural Characterization of [\{(C<sub>5</sub>Me<sub>5</sub>)ZrF<sub>2</sub>Cl\}<sub>4</sub>], [\{(C<sub>5</sub>Me<sub>5</sub>)HfF<sub>2</sub>Cl\}<sub>4</sub>], [(C<sub>5</sub>Me<sub>5</sub>)<sub>4</sub>Zr<sub>4</sub>(μ-F)<sub>2</sub>(μ-F<sub>2</sub>)<sub>2</sub>(μ-Cl)<sub>2</sub>Cl<sub>4</sub>], [(C<sub>5</sub>Me<sub>5</sub>)<sub>4</sub>Hf<sub>4</sub>(μ-F)<sub>2</sub>(μ-F<sub>2</sub>)<sub>2</sub>(μ-Cl)<sub>2</sub>Cl<sub>4</sub>], [(C<sub>5</sub>Me<sub>4</sub>Et)<sub>2</sub>ZrClF], and [(C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>HfClF]},
  author = {Eamonn F. Murphy and Thomas Lübben and Axel Herzog and Herbert W. Roesky and Alojz Demsar and Mathias Noltemeyer and Hans-Georg Schmidt},
  year = {1996},
  journal = {Inorganic Chemistry},
  doi = {10.1021/ic950822a},
  url = {https://doi.org/10.1021/ic950822a}
}

RIS

TY  - JOUR
TI  - First Mixed Fluoro−Chloro Group 4 Organometallics:  Synthesis and Spectroscopic and Structural Characterization of [{(C<sub>5</sub>Me<sub>5</sub>)ZrF<sub>2</sub>Cl}<sub>4</sub>], [{(C<sub>5</sub>Me<sub>5</sub>)HfF<sub>2</sub>Cl}<sub>4</sub>], [(C<sub>5</sub>Me<sub>5</sub>)<sub>4</sub>Zr<sub>4</sub>(μ-F)<sub>2</sub>(μ-F<sub>2</sub>)<sub>2</sub>(μ-Cl)<sub>2</sub>Cl<sub>4</sub>], [(C<sub>5</sub>Me<sub>5</sub>)<sub>4</sub>Hf<sub>4</sub>(μ-F)<sub>2</sub>(μ-F<sub>2</sub>)<sub>2</sub>(μ-Cl)<sub>2</sub>Cl<sub>4</sub>], [(C<sub>5</sub>Me<sub>4</sub>Et)<sub>2</sub>ZrClF], and [(C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>HfClF]
AU  - Eamonn F. Murphy
AU  - Thomas Lübben
AU  - Axel Herzog
AU  - Herbert W. Roesky
AU  - Alojz Demsar
AU  - Mathias Noltemeyer
AU  - Hans-Georg Schmidt
PY  - 1996
JO  - Inorganic Chemistry
DO  - 10.1021/ic950822a
UR  - https://doi.org/10.1021/ic950822a
ER  -

APA

Murphy, E. F., Lübben, T., Herzog, A., Roesky, H. W., Demsar, A., Noltemeyer, M., & Schmidt, H. (1996). First Mixed Fluoro−Chloro Group 4 Organometallics: Synthesis and Spectroscopic and Structural Characterization of [{(C5Me5)ZrF2Cl}4], [{(C5Me5)HfF2Cl}4], [(C5Me5)4Zr4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me5)4Hf4(μ-F)2(μ-F2)2(μ-Cl)2Cl4], [(C5Me4Et)2ZrClF], and [(C5Me5)2HfClF]. Inorganic Chemistry. https://doi.org/10.1021/ic950822a

Source records

crossref · retrieved 2026-09-26T01:13:16.519Z